This set is done using a nice magenta shade. It looks like a hidden gem in the midst of already beautiful gems. We’ve got a beautiful shade of blue that’s lightly marbled and is surrounded by gold foil. We have our nice flawless amethyst marbling, but the best part about it is the beautiful accent nail. I love how this greatly resembles what an amethyst tumbled stone actually looks like. This set has some nice big reflective stars that serve as a nice topper. These nails look like actual amethyst crystals. Instead, it’s a lot more subtle so that when the gold flakes are added it looks like stars in the night sky. The reason why these nails look so good is that their amethyst pattern isn’t too bold and bright. Who wouldn’t want their nails to look like the gorgeous night sky? Here we’ve got a mix of full purple glitter along with some light amethyst designs. We’ve got a blue translucent nail with some hints of white and a nice periwinkle topped with some pearls and gems. Here’s a captivating nail set to try out if you’re looking to try out two shades instead of one. These amethyst nails are done with a cooler shade of violet. I love how a lighter shade was used here as it looks like some white and purple smoke in clear glass. The amethyst pattern is painted on top of a nice clear nail base. This sort of design has been in trend these days! If there’s an intricate design you like, instead of having it printed all over your nails, you can have them painted on their edges instead. An amethyst stone with its natural cracks and sparkle. We have a nice full glitter nail and some marbled amethyst with gold foil. We have a nice deep violet gloss that’s topped with some nice gold gems. I love the purple vignette and the light marbled middle that gives some depth. A mixture of a beautiful crystal and a vast galaxy nail design. Here’s a simple gradient of colors that resemble the crystal. If you want an amethyst-inspired look but don’t really want anything too complicated. I also love the use of some deep violet crystals contrasted by the bright gems it’s surrounded by. This rich violet design has some nice blue flecks in its shimmer shade. Again, we’ve got some gold foil on top but the best part has to be the clear nail with nice reddish purple dried flower petals. This gives more of a frosted amethyst look. If you like this design, check out the moon and star nail art list as well. These resemble the beauty of the night sky. It’s definitely a look you could wear anywhere. The intricate design bordered by gold looks so opulent and clean at the same time. This looks like amethyst dripping off your nails. I think that the clear base makes it look so much cleaner. Here are some nice clear coffin nails with an amethyst pattern painted on top. The nice deep colors contrasted by the pops of white and gold make everything look so intricate. There’s a nice touch of gold foil on the edges making everything feel luxurious. Here’s a simple straight-to-the-point amethyst design. We’ve also got a nice touch of gold foil on top. We’ve got a really nice deep violet mixed with some white and purple. There are also two nice gold dots on the edge of the nail which ties it up nicely. Starting the list off with some nice watercolor amethyst nails. Whether you want a simple style to do yourself or some complex inspiration to show you nail tech, this list has something for you. If you want something truly unique for your next manicure, how about some Amethsy nail designs? Whether this is your birthstone or you just love this eye-catching shade there is something incredible about this trend gaining a modern twist.Īfter picking through thousands of different designs we’ve collected our favorites.
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She said that Priceline is exploring how AI can help its business. "We're all trying to solve the question of fast, efficient, low-fi creative that can be moved in and out of the market at the speed of consumer behavior," said Priceline SVP of strategy and brand marketing Lesley Klein. The biggest ad agencies are already using AI to create new ideas and increase productivity of their workers, and the Cannes Lions festival is a prime place for those people to share their insight. The rapid rise of generative AI took the advertising and media worlds by storm. Generative AI must boost creativity without stealing jobs "For any brand that considers members and allies of the LGBTQ+ community to be their customer or their audience, addressing or talking about the recent backlash to LGBTQ+ campaigns is appropriate, and in some cases, essential," she said. Now, Anheuser-Busch is in the awkward position of accepting the marketer of the year award at the upcoming festival.įura Johannesdottir, global chief creative officer at agency Huge, said she expects advertisers to evaluate how they address the issues faced by the LGBTQ+ community. Bud Light parent company Anheuser-Busch placed two marketers on leave, which reportedly angered its own employees. Bud Light sales dropped 17% year over year after it sent a personalized beer can to transgender influencer Dylan Mulvaney. Target pulled Pride merchandise nationwide after its staff were threatened. This year's Cannes Lions comes as US advertising and marketing executives are caught in the crux of the culture wars and wrestling with how best to show their support of LGBTQ+ communities, as right-wing backlash threatens to tank sales and share prices. Here are three other themes that are likely to dominate the chatter. But he argued that it's worth the effort and expense to be exposed to the latest marketing trends and the networking opportunities. Michael Kassan, CEO of MediaLink, a media and marketing consultancy owned by Hollywood talent agency UTA, said he's heard from some ad execs who feel going to Cannes is not good for optics due to economic challenges. Some 15,000 delegates are expected to hit the conference and awards show, even as economic concerns cause companies to cut back on attendees' expense accounts. The Cannes Lions organizers said that none of the three execs have been confirmed as speakers. Twitter's Elon Musk and Linda Yaccarino are widely expected to attend, as is Oliver Schusser, Apple's top executive on streaming and sports. When the Cannes Lions Festival of Creativity kicks off on June 19, it will be swarmed by top ad execs from giants like Apple, Twitter, TikTok, and Netflix who are relying on their burgeoning ad businesses to drive significant revenue in the near future.
Slater JC (1964) Journal of Chemical Physics 39:3199- Crystal Radii The bond length between atoms A and B is the sum of the atomic radii,ĬrystalMaker uses Atomic-Ionic radii data from: For example, the atomic-ionic radius of chlorine (Cl -) is larger than its atomic radius. These are the "realistic" radii of atoms, measured from bond lengths in real crystals and molecules, and taking into account the fact that some atoms will be electrically charged. CrystalMaker uses Van-der-Waals Radii data from:īondi A (1964) Journal of Physical Chemistry 68:441- Atomic-Ionic Radii Van-der-Waals radii are determined from the contact distances between unbonded atoms in touching molecules or atoms. Whilst this is straightforward for some molecules such as Cl 2 and O 2, in other cases one has to infer the covalent radius by measuring bond distances to atoms whose radii are already known (e.g., a C-X bond, in which the radius of C is known).ĬrystalMaker uses covalent radii listed on CrystalMaker-user Mark Winter's excellent Web Elements website. The covalent radius of an atom can be determined by measuring bond lengths between pairs of covalently-bonded atoms: if the two atoms are of the same kind, then the covalent radius is simply one half of the bond length. Springer Verlag, Berlin.Ĭlementi E, Raimondi DL, Reinhardt WP (1963). Vainshtein BK, Fridkin VM, Indenbom VL (1995) Structure of Crystals (3rd Edition). CrystalMaker uses Atomic radii data from two sources: Although more electrons are being added to atoms, they are at similar distances to the nucleus and the increasing nuclear charge "pulls" the electron clouds inwards, making the atomic radii smaller.Ītomic radii are generally calculated, using self-consistent field functions. Atomic radii decrease, however, as one moves from left to right, across the Periodic Table. The general trend is that atomic sizes increase as one moves downwards in the Periodic Table of the Elements, as electrons fill outer electron shells. Atomic RadiiĪtomic radii represent the sizes of isolated, electrically-neutral atoms, unaffected by bonding topologies. In the following article we'll explore a number of different sets of distinct atomic radius sizes, and later we'll see how you can make use of these "preset" values with CrystalMaker. Take the humble carbon atom as an example: in most organic molecules a covalently-bonded carbon atom is around 1.5 Ångstroms in diameter (1 Ångstrom unit = 0.1 nanometres = 10 -10 metres) but the same atom in an ionic crystal appears much smaller: around 0.6 Ångstroms. However, even for atoms of the same type, atomic radii can differ, depending on the oxidation state, the type of bonding and - especially important in crystals - the local coordination environment. To a first approximation we can regard atoms as "hard spheres", with an outer radius defined by the outer electron orbitals. How big is an atom? A simple question maybe, but the answer is not at all straighforward. The audience wants to know and love Kane, but can’t – so this need to love was displaced on to Welles himself, and accounted for his immense popularity and celebrity in the 1940s. Martin Scorsese, in his brilliant commentary on the film, said that cinema normally generates empathy for its heroes, but the enigma of Kane frustrates this process. Perhaps it is the fault of Citizen Kane itself, that mysterious, almost Elizabethan fable of kingship, which so seductively posits the coexistence of greatness and failure. As the room service waiter in the five-star hotel said to George Best: “Where did it all go wrong?” After all, he only created arguably the greatest Hollywood movie in history, only directed a string of brilliant films, only won the top prize at Cannes, only produced some of the most groundbreaking theatre on Broadway, only reinvented the mass medium of radio, and in his political speeches, only energised the progressive and anti-racist movement in postwar America. Poor, poor Orson Welles: repeatedly talked about as a tragic disappointment, his achievements somehow held against him, as if he had culpably outlived his own genius. Then the major Hollywood studios gave him the chance to direct big-budget pictures, over which he gained more and more artistic control until he made his culminating mature masterpiece: Citizen Kane, the story of the doomed press baron Charlie Kane – played by Welles himself, partly based on WR Hearst – and told in a dazzling series of fragments, shards, jigsaw pieces and reflected images. The idea, effectively, is that Welles started life as a fat actor who got his first break doing TV commercials for wine, moved on to bigger character roles as fat men, but used his fees to help finance indie films which he directed himself their modest, growing success gave him the energy and self-esteem to lose weight. S pitting Image once made a joke about Orson Welles – that he lived his life in reverse. From the Start menu search, look for “Windows Update Settings” and check for the latest updates, even if it shows “You’re up to date.One of them is KB5008295, but you should opt for the latest OOB patches whenever they’re announced. The universal solution to the Snipping Tool not working issue in Windows 11 is to finish an “Out-of-band (OOB)” update: a non-security Microsoft patch introduced past scheduled release dates. Check for Windows 11 Out-of-Band (OOB) Updates When you release your mouse or trackpad button, the image is captured. After pressing the keys, drag the crosshair to select the area of the screen to capture. Each solution covered below will fix a unique error source. Allows you to capture a portion of the screen that you select. Screenshots are useful for capturing snapshots of programs or windows that you have open on your computer. Snip & Sketch is a Microsoft product, meaning that its. The Snipping Tool not working can be traced to faulty Windows 11 security updates, expired digital certificates, or a missing folder/registry value. This feature is available in Excel, Outlook, PowerPoint, and Word. The program has come installed in Windows 10 as an included feature since October 2018. In Windows 10, you can select which one you want to use by clicking. How to Fix the Windows 11 Snipping Tool Not Working There are four types of screen captures you can take with the Microsoft Snipping Tool app. Do a Cloud "Reset" of the Windows 11 Operating System that lets you capture your screen, annotate it with voice and ink, and easily share with. While Snipping Tool came built into Windows, currently you need to download Snip and Sketch through Microsoft’s online store. Use Local Group Policy Editor in Windows 11 to Enable Snipping Tool Set Keyboard Print Screen Key to Launch Snipping Tool You’ll see four choices here: Free-form Snip. Turn Background App Permissions On to Take Pictures To take a screenshot with the Snipping Tool, click the down arrow to the right of the New button. Keep "Automatically Copy Changes" Enabled in Snipping Tool Settings Run the Windows 11 Snipping Tool Directly from "Windows.old" Folder Disable Automatic Time Temporarily and Reset Its Manual Value Snip & Sketch interface is better than the Snipping Tool and the app is also picking up advanced features with updates through Store. M Marie Wurdeman 65 followers More information Find this Pin and more on Music by Marie Wurdeman. Out went the lady with the alligator purse. Lyrics: I had a little turtleHis name is Tiny TimI put him in the bathtubTo see if he could swim.He drank up all the waterHe ate up all the soapAnd now hes. Nothing! said the lady with the alligator purse. Turtle Song Lyrics: I Had a Little Turtle display poster > Unlimited Premium Download I Had a Little Turtle Nursery Song Display Poster (Tiny Tim) 4. Mumps said the doctor, measles said the nurse, In came the lady with the alligator purse. Miss Lucy called the lady with the alligator purse. Miss Lucy called the doctor, Miss Lucy called the nurse, He tried to eat the bathtub but it wouldn't go down his throat He drank up all the water, he ate up all the soap Tiny Tim There was a little turtle, His name was Tiny Tim, I put him the bathtub, To see if he could swim. She put him in the bathtub to see if he could swim Miss Lucy had a baby, his name was Tiny Tim, Turtle Song Lyrics: 'I Had a Little Turtle' display poster Unlimited Premium Download I Had a Little Turtle Nursery Song Display Poster (Tiny Tim) 4. Oh, bubble bubble bubble, bubble bubble bubble,īubble bubble bubble, bubble bubble bubble. He drank up all the water, he ate up all the soap,Īnd when he woke up in the morning he had bubbles in his throat. I put him in the bathtub to see if he could swim. I had a little turtle, his name was Tiny Tim, Thanks to my colleague Erie who introduced me to The Lady via Nadine Bernard Westcott’s excellent book. I’ve included a fairly common version of The Lady With the Alligator Purse. The tune belongs to an old playground/skipping song so there are numerous variants, some less storytime-appropriate than others. I usually sing I Had a Little Turtle without an instrument so I can demonstrate the hand gestures, but I’ve played the ukulele version for my toddler and his buddies and they loved it that way too. And an iPad works as a hub only when it’s actually in your home if you travel with it, you’ll no longer have Wi-Fi access to the lock. There’s another important aspect to consider here: Although the Encode Plus has built-in 2.4GHz Wi-Fi, meaning you can control it and get status updates even when away from home, that option isn’t available to Apple Home users unless you also have a hub: Apple TV, HomePod Mini, or iPad. (To delve into settings, you have to long-press the lock icon, then tap a gear icon.) The Home app by itself makes for a confusing (and limited) Encode Plus manager, as there’s no obvious way to do anything but toggle between lock and unlock. The manual suggests choosing one or the other, but I learned that without the latter, you don’t have access to most of the lock’s settings and options. For starters, it’s not clear whether you should use only the Apple Home app or install the Schlage app as well. What we don’t like Apple Home Key setup can be a painĪlthough the Schlage smart lock hardware installs with minimal fuss, Apple users may get a little frustrated by the software part. This all but guarantees protection against porch-piracy, though of course you need to be comfortable with strangers stepping foot across the threshold. Once activated, delivery drivers can unlock your door (without the need for any manual code-sharing or the like) and place packages inside, then lock it again. If you have concerns about package theft, you’ll appreciate the Encode Plus’ support for Amazon Key. The lock supports Amazon Key in-home deliveries And I found it frustrating that my Apple Watch kept asking me if I wanted to run this automation instead of just, you know, running it. But this works only if you have a hub, as described later in the review. This potentially solves the “phone-dead-now-what” problem, though obviously you could just use the lock’s keypad if needed.Īs for automation, Apple’s HomeKit handles that: You can toggle a setting that will automatically unlock the Encode Plus when you get home and lock it again when you leave. That’s because NFC, an ultra-low-power technology, can transmit even when there’s not enough juice to power the phone itself. What’s more, Schlage promises that Home Key will work even if your iPhone has a dead battery (though only within about five hours of that happening). The end result is impressive: Just bring your device within an inch or two of the keypad and it locks or unlocks almost immediately. Typically this is handled via Bluetooth, but the Encode Plus Schlage smart lock leverages Apple’s new Home Key protocol, which adds a digital, NFC-powered “key” to Apple Wallet and Watch. Most smart locks incorporate one or more proximity features, meaning they can unlock when your phone comes near or unlock if it leaves the area. And of course there’s always the option of a mechanical key. If you have an Amazon, Apple or Google smart device in your home, the lock will respond to voice commands. You can unlock the Schlage Encode Plus Wi-Fi deadbolt by tapping your iPhone or Apple Watch to the keypad until the light turns green.Īs you’d expect from a modern smart lock, this one includes a digital keypad with support for up to 100 custom codes, which you can add or remove easily from within the Schlage app. (12) He travels in stratospheric circles with crowned heads, presidents and various illuminati, glitterati and cognoscenti. (9) At the Vogue awards, she told the assembled industry illuminati : ├ö├ç├┐I would like to thank my mum - I give this to her.├ö├ç├û (10) some mysterious standard known only to the illuminati of the organization (11) Their names should be spoken among the illuminati of our culture. (8) Celebrities, journalists, and other illuminati have long gushed with admiration for Cuba's communist despot. (7) There are a few weak-hearted souls who would like to raise the issue, but they recognize that the illuminati are not likely to entertain such a discussion any time soon. (6) No one is immune to the dollar sign, but the top illuminati can get it from many places, so the writing has to be on the page as well as on the checks. (5) The danger is that the illuminati are cutting off their nose to spite their face. (4) Without attention spans we will never see what is really there and we will spend all of our time concerned with the ideas and things that the illuminati want us to waste our times with rather than seeing the bigger picture. (3) They hosted a series of environmental soirÔö£┬«es at their studio to air important issues and Galen was always as well informed as anyone there, which included such illuminati as David Brower, Mark Dowie, and John McCosker. (2) In the last year rumours drifted forth that the BBC illuminati had no intention of allowing either the Jubilee or the possible death of the Queen Mother to be a time with nothing but deferential respect. (1) Each of these illuminati was paid $30,000 to attend the conference. You can even download MP3 songs for offline listening. Songs are the best way to live the moments or reminisce the memories and thus we at Wynk strive to enhance your listening experience by providing you with high-quality MP3 songs & lyrics to express your passion or to sing it out loud. His fan base alone will make this the most popular song, but it’s arguably a dull and predictable let down (and that’s coming from one of those Em fans). With Wynk Music, you will not only enjoy your favourite MP3 songs online, but you will also have access to our hottest playlists such as English Songs, Hindi Songs, Malayalam Songs, Punjabi Songs, Tamil Songs, Telugu Songs. A noticeable absence thus far, Eminem pops up on the penultimate track Medicine Man. Wynk Music brings to you Medicine Man MP3 song from the movie/album Compton. The City of Fawn Creek is located in the State of Kansas. Download & Play Compton MP3 songs offline free on Hungama Gold. Dre from Compton album online on Hungama. PaakĪndré Romell Young, Marshall Mathers, Candice Pillay, J. Listen to Medicine Man MP3 Song Free by Dr. Intro: Candice Pillay Don't let me find out, the bitch in you Don't let me find out, the snitch in you Hook: Candice Pillay Fame and fortune It's not your fortune Fuck the world now I'm done with foreplay Doctor's orders Go fuck yourself Take two a day Set them on an overdose And kill yourself Doctor's orders Verse 1: Dr. Dre, Eminem, Candice Pillay, Anderson. You can even download MP3 songs for offline listening.Dr. With Wynk Music, you will not only enjoy your favourite MP3 songs online, but you will also have access to our hottest playlists such as English Songs, Hindi Songs, Malayalam Songs, Punjabi Songs, Tamil Songs, Telugu Songs. biopic Straight Outta Compton. Dre, a supposedly final effort that was 'inspired' by the N.W.A. Wynk Music brings to you Medicine Man MP3 song from the movie/album Compton. Dre Track 15 on Compton Featuring Candice Pillay, Anderson. Dre album was supposed to be The Detox, but that once-mythical, canceled LP was replaced by Compton: A Soundtrack by Dr. The song features vocals from fellow American rapper Eminem, South African singer Candice Pillay, and American recording artist Anderson. Dre, from his third studio album Compton. PaakĪndré Romell Young, Marshall Mathers, Candice Pillay, J. About Medicine Man 'Medicine Man' is a song by American rapper Dr. Chapters can also be played in two-player local co-op multiplayer. Performance is ranked, with the best performance rewarding a Balan Statue upon first completion, and multiplying the current Drop total. Taking on the role of Balan, players engage in a series of quick time events, matching Balan's poses with button presses. A recurring minigame activated by finding a top hat in levels is Balan's Bout. Minigames can be unlocked and played within each chapter using special costumes, such as a football-themed challenge. If the player character is hit without a costume, they are ejected from the Chapter. Receiving damage, or falling off the edge of the environment, causes the equipped costume to disappear. Only three costumes can be held at a time when a fourth costume is acquired, the costume it replaces is sent into a costume bank which can be accessed at checkpoints. 80 costumes are spread throughout the stages, some of them in secret locations. When not wearing a costume, Leo and Emma's only available actions are jumping and basic movement. Costumes grant abilities such as hovering, navigating particular hazards and paths, or fighting enemies. While exploring, Leo and Emma find costumes from the cast of each chapter these are unlocked using collectible keys. The game uses adaptive difficulty, adjusting the number and types of enemies based on player performance both on the initial playthrough and return playthroughs of stages. Each chapter ends with a boss battle themed after the Chapter's environment and narrative. During exploration, enemies called Negati will appear and attack the player character. A simple control scheme is used, with two buttons used to change between costumes, and other actions aside from character and camera movement mapped to all other buttons. Collectables include Balan Statues and crystalline objects called Drops. Within each chapter, Leo and Emma must navigate through a sandbox environment, searching areas for collectables and solving puzzles to progress to the end of the level. In the beginning, only the first chapter is available, collecting items called Balan Statues in each area will unlock Chapters. The game plays out across twelve multi-level areas called Chapters. Gameplay from Balan Wonderworld the player character (centre) uses a costume ability to traverse the environment.īalan Wonderworld is a platform game where players take on the role of either Leo Craig or Emma Cole, two children drawn into the magical realm of Wonderworld by a being called Balan. Critics panned its gameplay and design, although some praised its graphics and music. The game received generally negative reviews and underperformed commercially. Square Enix also published a novelization by Kawasaki. There were subsequent claims from Naka and other employees regarding internal conflict around the game's quality and marketing.īalan Wonderworld was released worldwide for Nintendo Switch, PlayStation 4, PlayStation 5, Windows, Xbox One, and Xbox Series X/S on 26 March. The cutscenes were created by Visual Works. The music, composed by Ryo Yamazaki and Hironori Anazawa, emulates musical scores and includes vocals from West End performers such as Laura Pitt-Pulford. The scenario was written by novelist Soushi Kawasaki. The aesthetic was based on musical theater, and Naka studied the hero's journey when creating the story draft. Development began in 2018 it was Naka's first collaboration with artist Naoto Ohshima since Sonic Adventure (1998). They explore levels, collecting items to progress to further areas and using a variety of powers unlocked using themed costumes.īalan Wonderworld is the debut project of Balan Company, a subsidiary brand of Square Enix led by Yuji Naka, the co-creator of Sonic the Hedgehog and Nights into Dreams. Assuming the role of two children guided by a magical being called Balan, the player explores twelve worlds themed after the hearts of troubled individuals. Balan Wonderworld is a 2021 platform game principally developed by Arzest and published by Square Enix. |